The British government said it would provide Ukraine with 650 lightweight multi-role missiles worth $213.13 million, to help protect the country from Russian drones and bombing.
Last week Russia unleashed its largest air attack on Ukraine since the full-scale war began early in 2022. Ukraine has made repeated requests for more air defence support to defend itself from missile and drone attacks.
The new supply of missiles was announced as British defence minister John Healey attended the Ukraine Defence Contact Group, an ad-hoc coalition of some 50 nations, at a US air base in Germany.
The Ministry of Defence said, in keeping with the new government's commitment to speed deliveries of aid to Ukraine, the first batch of missiles announced on Friday were expected to arrive by the end of the year.
"This new commitment will give an important boost to Ukraine's air defences," Healey said in a statement.
The Ministry of Defence said the missiles made by Thales have a range of more than six kilometres (3.73 miles) and can be fired from a variety of platforms on land, sea, and air.
Last Monday, Russia fired more than 200 missiles and drones at Ukraine, killing seven people and striking energy facilities nationwide in what Kyiv called the war's "most massive" attack.
Russia and Ukraine each exchanged 307 of their service personnel on Saturday on the second day of a prisoner exchange that, when completed, is set to be the largest such swap in the three-year war between the two countries.
U.S. President Donald Trump has suggested the prisoner swap - which should see 1,000 prisoners released on each side over three days - could herald a new phase in stop-start efforts to negotiate a peace deal between Moscow and Kyiv.
Saturday's swap was announced by Russia's defence ministry, and separately by Ukrainian President Volodymyr Zelenskiy in a post on social
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Russia launched dozens of attack drones and ballistic missiles at Kyiv overnight in one of the biggest combined aerial attacks on the Ukrainian capital of the three-year war, damaging several apartment buildings and injuring at least 15 people.
Rescuers on Friday pulled out all 260 mine workers who had been stuck for more than 24 hours in an underground shaft in South Africa, the mine's operator said.
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